摘要
Graphene is the most attractive carbon-based material at present and attracting increasing attention as promising candidates for applications in numerous areas, because of its extraordinary chemical, thermal and mechanical properties. In this paper, we discussed an innovative and simple method to synthesize titanium dioxide （TiO2） nanoclusters, using graphene as a mid-step template not as a component of final product. Using this method, the graphene was firstly fully coated with TiO2 nanoparticles by the thermal decomposition of titanium （IV） isopropoxide in a supercritical carbon dioxide （SC-CO2） at 200 ℃; the developed TiO2/graphene composites then were heated in an oxygen atmosphere. Eventually the TiO2 nanoclusters were obtained. The prepared TiO2 nanoclusters showed irregular features with high surface coverage, providing promises in a wide range of applications, especially for photo-degradation of organic compounds in aqueous solution under the radiation of UV-light.
Graphene is the most attractive carbon-based material at present and attracting increasing attention as promising candidates for applications in numerous areas, because of its extraordinary chemical, thermal and mechanical properties. In this paper, we discussed an innovative and simple method to synthesize titanium dioxide （TiO2） nanoclusters, using graphene as a mid-step template not as a component of final product. Using this method, the graphene was firstly fully coated with TiO2 nanoparticles by the thermal decomposition of titanium （IV） isopropoxide in a supercritical carbon dioxide （SC-CO2） at 200 ℃; the developed TiO2/graphene composites then were heated in an oxygen atmosphere. Eventually the TiO2 nanoclusters were obtained. The prepared TiO2 nanoclusters showed irregular features with high surface coverage, providing promises in a wide range of applications, especially for photo-degradation of organic compounds in aqueous solution under the radiation of UV-light.
基金
financial support from iNANO through the Danish National Research Foundation
the National Natural Science Foundation of China to the Sino-Danish Center of Excellence on"The Self-assembly and Function of Molecular Nanostructures on Surfaces"
the Carlsberg Foundation
the Villum Foundation
the National Natural Science Foundation of China(No.51003021)
China Postdoctoral Science Special Foundation(Nos.201003420 and20090460067)
UTC Exploration Project(CASC-HIT12-1C03)
Opening Project of Key Laboratory of Solid Waste Treatment and Resource Recycle,Ministry of Education(12zxgk10)
Harbin City Science and Technology Projects(2013DB4BP031)
