摘要
两段炉气化是一种比较成熟的煤炭气化工艺,多用于中小城镇煤气生产。两段炉气化废水水质成分复杂,废水中含有高浓度氨氮、酚类、氰化物、喹啉、吡啶、吲哚、呋喃、咪唑、萘、胺类和氯代物等难降解物质,是典型的一类高浓度难降解的有机物废水,其特点是含油高,难降解有机物浓度含量高,毒性很大,以及可生化性极差,通常B/C小于0.1。因此此类废水很难用传统的生化处理工艺进行降解。本文通过采用紫外-芬顿高级氧化方法对两段炉气化废水进行预处理试验研究,发现当氧化剂H202浓度为10%o~30‰时,可较明显地提高废水的可生化性B/C至0.5以上。
Abstract:The two-stage gasifier is a relatively mature coal gasification process which was frequently used for SNG production for medium and small towns. The effluent from two-stage gasification is complicated, containing high concentration of non-degradable substance such as ammonia, phenol, cyanide, quinoline, pyridine, indole, furan, imidazole, naphthalene, amines and chlorinated materials etc.. The gasification effluent is a typical high concentration of refractory organic wastewater with characteristics of high oil content, high concentration of organic compounds, high toxicity and poor biodegradability, and its biodegradability value ( B/C ) is always lower than 0. 1. Therefore, it is very difficult to use traditional biological treatment to degrade this kind of wastewater. In this oaoer, the methnd nf UV-Fenton advanced oxidation was used for degradability of wastewater( B/C ) could the be treatment of the two-stage gasification effluent, it was found that the bio- significantly increased to higher than 0.5 when the oxidant concentration of H2O2 was 10‰-30‰.
出处
《新疆环境保护》
2015年第3期27-32,共6页
Environmental Protection of Xinjiang
基金
科研院所技术开发研究专项资助项目(2014EG122191)
国家高技术研究发展计划(863计划)(2015AA050501)
关键词
气化废水
可生化性
紫外-芬顿
Coal gasification wastewater
Treatment Biodegradability
UV-Fenton