摘要
在水溶液中制备了络合物[Cu(H_2O)_2(en)][SO_4]的晶体,并在室温下测定了该晶体在近紫外—可见—近红外区域的电子吸收光谱。应用配位场理论以及3d轨道波函数径向标度理论定量地解释了晶体的电子吸收光谱。
The crystal of the title compound is synthesized in aqueous solution. The electronic absorption spectrum is determined at room temperature. By using the ligand field theory and 3d orbits wave radial scaling theory, the d—d transition spectrum is interpreted quantitatively.
关键词
电子吸收光谱
络合物
晶体结构
electronic absorption spectrum, scaling radial theory, complex.
