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Iron-catalyzed aerobic oxidative amidation of tertiary amines with carboxylic acids

Iron-catalyzed aerobic oxidative amidation of tertiary amines with carboxylic acids
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摘要 An oxidative amidation of tertiary amines with carboxylic acids has been developed in the presence of FeC13- 6H20 as catalyst and oxygen as oxidant. A variety of tertiary amides were obtained in good to excellent yields from inexpensive and readily available reagents. The possible reaction pathways were investigated. An oxidative amidation of tertiary amines with carboxylic acids has been developed in the presence of Fe Cl3·6H2O as catalyst and oxygen as oxidant.A variety of tertiary amides were obtained in good to excellent yields from inexpensive and readily available reagents.The possible reaction pathways were investigated.
出处 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第8期1310-1315,共6页 中国科学(化学英文版)
基金 financially supported by the Fundamental Research Funds for the Central Universities the Research Funds of Renmin University of China(10XNL017)
关键词 AMIDATION tertiary amine carboxylic acid iron catalysis OXIDATION 氧化剂 催化剂 酰胺 羧酸 叔胺 反应途径
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