摘要
A Mg-14.28Gd-2.44Zn-0.54Zr (mass fraction, %) alloy was prepared by conventional ingot metallurgy (I/M). The microstructure differences in as-cast and solution-treated alloys were investigated. Sliding tribological behaviors of the as-cast and solution-treated alloys were investigated under oil lubricant condition by pin-on-disc configuration. The wear loss and friction coefficients were measured at a load of 40 N and sliding speeds of 30-300 mm/s with a sliding distance of 5000 m at room temperature. The results show that the as-cast alloy is mainly composed ofα-Mg solid solution, the lamellar 14H-type long period stacking ordered (LPSO) structure within matrix, andβ-[(Mg,Zn)3Gd] phase. However, most of theβ-phase transforms to X-phase with 14H-type LPSO structure after solution heat treatment at 773 K for 35 h (T4). The solution-treated alloy presents low wear-resistance, because the hard β-phase is converted into thermally-stable, ductile and soft X-Mg12GdZn phase with LPSO structure in the alloy.
利用传统的熔铸法制备Mg-14.28Gd-2.44Zn-0.54Zr合金,研究铸态和固溶态合金的微结构。利用销-盘装置研究铸态和固溶态合金的室温润滑滑动摩擦磨损行为研究。在外载荷为40 N,滑动速度为30-300 mm/s以及滑行路程为5000 m情况下,测量磨损率和摩擦因数。研究结果表明:铸态合金主要由α-Mg固溶体、分布在基体内的层片状的14H型长周期结构(LPSO)和β-[(Mg,Zn)3Gd]相组成。经过温度为773 K固溶处理35 h后,大量的β相转变成具有14H型X相LPSO结构。由于固溶处理后大量β相转变为热稳定的韧性X-Mg12Gd Zn长周期结构相,固溶合金呈现较低的抗磨损能力。
基金
Projects(51304135,50971089)supported by the National Natural Science Foundation of China
Project(A1420110045)supported by National Defense Basic Research Plan,China
Project(11QH1401200)supported by the Shanghai Phospherus Program,China
Project(NCET-11-0329)supported by the New Century Excellent Talents in University of Ministry of Education of China