摘要
The bimetallic hexanuclear cluster [Mn4Ni2O2（Cl-Sao）6.（CH3OH）8].10CH3OH （1） was synthesized. Single-crystal X-ray analysis reveals that 1 consists of two [Mn2Ni（μ3-O）（Cl-Sao）3] subunits linked together via two pairs of long Ni-O bonds involving two oximate oxygen atoms and two phenolate oxygen atoms. Each Mn and Ni center achieves six-coordination with axial methanol molecules. The spin centers of the Mnm and Niu ions exchange magnetic coupling through O2-, O-phenolate and -N-O- bridges. The magnetic properties of the cluster have been investigated.
The bimetallic hexanuclear cluster [Mn4Ni2O2（Cl-Sao）6.（CH3OH）8].10CH3OH （1） was synthesized. Single-crystal X-ray analysis reveals that 1 consists of two [Mn2Ni（μ3-O）（Cl-Sao）3] subunits linked together via two pairs of long Ni-O bonds involving two oximate oxygen atoms and two phenolate oxygen atoms. Each Mn and Ni center achieves six-coordination with axial methanol molecules. The spin centers of the Mnm and Niu ions exchange magnetic coupling through O2-, O-phenolate and -N-O- bridges. The magnetic properties of the cluster have been investigated.
基金
support from the Natural Science Foundation of China(NSFC)(No.21171021)
Beijing National Laboratory for Molecular Sciences(BNLMS)
Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry
