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Calculation method of quantum efficiency to TiO_2 nanocrystal photocatalysis reaction 被引量:4

Calculation method of quantum efficiency to TiO_2 nanocrystal photocatalysis reaction
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摘要 The quantum yield is an important factor to evaluate the efficiency of photoreactor. This article gives an overall calculation method of the quantum efficiency( Φ ) and the apparent quantum efficiency( Φ a) to the TiO 2/UV photocatalysis system. Furthermore, for the immobility system (IS), the formulation of the faction of light absorbed by the TiO 2 thin film is proposed so as to calculate the quantum efficiency by using the measured value and theoretic calculated value of transmissivity (T). For the suspension system(SS), due to the difficulty to obtain the absorption coefficient ( α ) of TiO 2 particulates, the quantum efficiency is calculated by means of the relative photonic efficiency ( ζ r) and the standard quantum yield ( Φ standard ). The quantum yield is an important factor to evaluate the efficiency of photoreactor. This article gives an overall calculation method of the quantum efficiency( Φ ) and the apparent quantum efficiency( Φ a) to the TiO 2/UV photocatalysis system. Furthermore, for the immobility system (IS), the formulation of the faction of light absorbed by the TiO 2 thin film is proposed so as to calculate the quantum efficiency by using the measured value and theoretic calculated value of transmissivity (T). For the suspension system(SS), due to the difficulty to obtain the absorption coefficient ( α ) of TiO 2 particulates, the quantum efficiency is calculated by means of the relative photonic efficiency ( ζ r) and the standard quantum yield ( Φ standard ).
出处 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2002年第1期70-75,共6页 环境科学学报(英文版)
关键词 photodegradation reaction quantum efficiency apparent quantum efficiency photonic efficiency relative photonic efficiency absorption coefficient photodegradation reaction quantum efficiency apparent quantum efficiency photonic efficiency relative photonic efficiency absorption coefficient
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