摘要
本文测定了1,4,8,11—四甲基,1,4,8,11—四氮杂环十四烷合镍(Ⅱ)配合物(简写为Ni(tmc)^(2+)下同)在一系列配位溶剂中配合反应的△H^(?)、△S^(?)、△G^(?)及由异构体R,S,R,S—Ni(tmc)^(2+)转变为异构体R,R,s,s—Ni(tmc)^(2+)的反应速率。
In this paper we measured the coordinating equilibrium themodynamic parameters of the complex 1, 4, 8, 11—tetramethy—1, 4, 8, 11—tetraazacyclotetradecane nickel(Ⅱ) (R, S, R, S—Ni (tmc)^(2+)), in coordinating solvents and the rate constants that the isomer B (R, S, R, S—Ni(tmc)^(2+) is transformed in to isomer A(R, S, S, R—Ni (tmc)^(2+))
出处
《郑州大学学报（自然科学版）》
1991年第2期68-72,共5页
Journal of Zhengzhou University (Natural Science)
