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活性炭载体对聚合物电解质膜燃料电池中炭载铂电催化剂性能的影响 被引量:18

Effect of Properties of Active Carbon Supports on Performance of Pt/C Catalysts in Polymer Electrolyte Membrane Fuel Cell
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摘要 分别以松木炭和VulcanXC 72炭为载体制得炭载铂电催化剂 ,在聚合物电解质膜燃料电池 (PEMFC)中对其性能进行了比较。结果表明 :VulcanXC 72炭作载体的电催化剂性能显著优于松木炭作载体的电催化剂 ,利用多种分析方法对活性炭的物理和表面化学性质进行了系统的研究 ,发现活性炭的孔径。 The Pt/C catalysts were prepared with pine active carbon and Vulcan XC-72 active carbon as the supports. The performances of the Pt/C catalysts in polymer electrolyte membrane fuel cell were compared. The result indicates that the performance of Pt/Vulcan XC-72 is better than that of Pt/pine. The physical and chemical properties of the two active carbons were measured using several analysis techniques. It was found that the pore size, specific conductivity and the surface function group significantly influence the performance of the electrocatalyst.
出处 《分析化学》 SCIE EI CAS CSCD 北大核心 2002年第7期788-791,共4页 Chinese Journal of Analytical Chemistry
基金 科技部"973"项目 (No .G2 0 0 0 0 2 6 40 8) 国家自然科学基金 (No .2 0 0 0 30 0 5 ) 江苏省科委基金 (No .BQ2 0 0 0 0 0 0 9) 吉林省科委基金(No .2 0 0 0 0 5 10 )资助课题
关键词 活性炭 炭载铂电催化剂 聚合物由解质膜燃料电池 催化性能 polymer electrolyte membrane fuel cell active carbon platinum electrocatalysis
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