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城市生活垃圾热解特性的TG-DSC分析 被引量:33

TG-DSC STUDY ON PYROLYSIS CHARACTERISTICS OF MUNICIPAL SOLID WASTES
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摘要 Seven typical components in municipal solid wastes (MSWs)--paper,food,textile,wood,straw,plastic and rubber were chosen as the thermogravimetric analysis samples in this paper to study the pyrolysis characteristics. By the thermogravimetry and differential scanning calorimetry (TG-DSC) analysis,pyrolysis characteristics of MSWs’ components and pyrolysis endothermal enthalpy were obtained.The kinetic parameters of pyrolysis were determined with the Doyle method and a multi-stage first order pyrolysis model was proposed.The simulated results by this model showed good agreement with the TG experimental data.The pyrolysis characteristics provide significant parameters to a new concept of circulating fluidized bed incinerator,which can simultaneously restrain the high-temperature HCl corrosion and emission of dioxins. Seven typical components in municipal solid wastes (MSWs)--paper,food,textile,wood,straw,plastic and rubber were chosen as the thermogravimetric analysis samples in this paper to study the pyrolysis characteristics. By the thermogravimetry and differential scanning calorimetry (TG-DSC) analysis,pyrolysis characteristics of MSWs' components and pyrolysis endothermal enthalpy were obtained.The kinetic parameters of pyrolysis were determined with the Doyle method and a multi-stage first order pyrolysis model was proposed.The simulated results by this model showed good agreement with the TG experimental data.The pyrolysis characteristics provide significant parameters to a new concept of circulating fluidized bed incinerator,which can simultaneously restrain the high-temperature HCl corrosion and emission of dioxins.
出处 《化工学报》 EI CAS CSCD 北大核心 2002年第7期759-764,共6页 CIESC Journal
关键词 TG-DSC分析 城市生活垃圾 热重分析 差示扫描量热分析 热解特性 动力学参数 焚烧 垃圾发电 垃圾处理 MSWs,thermogravimetry,differential scanning calorimetry,pyrolysis characteristics,kinetic parameters
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