摘要
本文用正辛烷代替汽油从理论和实验两方面研究了水碳比变化对汽油氧化重整制氢反应的影响。理论研究表明 ,在绝热反应条件下 ,对应确定的反应温度存在一个最佳的氧油比及水碳比 ;实验研究表明 ,在非绝热反应体系中 ,在一定的氧油比及反应温度条件下 ,反应体系的转化率及生成氢的选择性均随水碳比的增加而增加 ,为实现燃料电池汽油制氢自热反应 ,反应体系应在一定水碳比条件下进行 ,实验条件下最佳的水碳比范围是 1.5— 2 .5之间。
Those effects of water/carbon ratios on partially oxidizing and steam reforming of gasoline, which used n-octane as reactant, have been investigated in this paper. The theory analysis showed that the reaction had optimum ratios of water/carbon and oxygen/oil at certain reaction temperature in the condition of adiabatic reaction. The experimental results showed that the conversion efficiency of n-octane and the selectivity of production hydrogen were increased with water/carbon ratio at certain reaction temperature and oxygen/oil ratio in the condition of non-adiabatic reaction. The reaction should be carried out at certain water/carbon ratios in order to produce hydrogen for fuel cell by gasoline without supplying energy to the reaction system. The optimum ratios of water/carbon were in the range of 1.5-2.5 in the experimental conditions.
出处
《环境污染治理技术与设备》
CSCD
北大核心
2002年第6期29-32,共4页
Techniques and Equipment for Environmental Pollution Control
关键词
汽油
氧化重整
制氢
水碳化
gasoline
oxidizing and reforming
hydrogen production
water/carbon ratio
