摘要
在用酯基锡MeO2CCH2CH2SnCl3合成配合物MeO2CCH2CH2SnCl3·(2-OHC6H4CH=NC6H5)时,其配合物的甲苯溶液放置培养单晶时(放置十天以上)会发生分解生成配合物MeO2CCH2CH2SnCl4—·H+。研究了标题化合物的合成反应,用元素分析、IR、NMR对配合物进行了表征,并测定了晶体结构。为正交晶系,空间群为P2cn, a=7.852(2), b=12.236(1), c=16.952(4) ? V=1628.7?, Z=4, Dc=1.79g/cm3, F(000)= 860,m=22.2cm—1(Mo),R=0.0449, Rw=0.0382。标题化合物的空间构型为畸变的八面体构型,中心锡原子的配位数为6。
The anion of MeO2CCH2CH2SnCl4 - was obtained by decomposing the yellow solution of MeO2CCH2CH2SnCl3.(2-OHC6H4CH=NC6H5) by standing for 15 days, which is the product of 3-methoxy-carbonylethyltin trichlorides with Schiff base (2-OHC6H4CH=NC6H5). The title compound was characterized by elemental analysis, IR. H-1 NMR,C-13 NMR and X-ray diffraction analysis. The crystal of the title compound belongs to orthorhombic system, space group P2cn, a=7.852(2), b=12.236(1),c=16.952(4)Adegrees, V=1628.7 Angstrom(3), Z=4, D-c=1.79g/cm(3) F(000)=860, mu=22.2cm(-1), R=0.0449, Rw=0.0382. The title compound exists as a discrete molecule, and the tin atom attains a distorted octahedral geometry via the coordination of intramolecular carbonyl oxygen and chloride ion. The coordination number of tin atom is 6.
基金
国家自然科学基金(批准号:29170084)
山东省科委基金(批准号:983000001)资助课题
