摘要
Co-liquefaction of coal and sawdust was studied in the presence of hydrogen-donor solvent, tetralin. Coal samples were prepared through floatation of the Xinwen coal, followed by enrichment of maceral constituents. Sample I was rich in vitrinite and Sample II fusinite. Effects of reactiontemperature, time and initial cold H2 pressure were studied on conversion, yield, especially oil yield,through comparison between these two samples. Because it is more difficult to be liquefied, Sample II, is greatly affected by changes in temperature and time. However, it is almost independent of change ininitial cold H2 pressure, owing to the role of tetralin as hydrogen vehicle. Certain product(s) formed from thermolysis of sawdust can help hydrogenation of the intermediate (asphaltene and preasphaltene) infurther forming oil products.
Co-liquefaction of coal and sawdust was studied in the presence of hydrogen-donor solvent, tetralin. Coal samples were prepared through floatation of the Xinwen coal, followed by enrichment of maceral constituents. Sample I was rich in vitrinite and Sample II fusinite. Effects of reactiontemperature, time and initial cold H2 pressure were studied on conversion, yield, especially oil yield,through comparison between these two samples. Because it is more difficult to be liquefied, Sample II, is greatly affected by changes in temperature and time. However, it is almost independent of change ininitial cold H2 pressure, owing to the role of tetralin as hydrogen vehicle. Certain product(s) formed from thermolysis of sawdust can help hydrogenation of the intermediate (asphaltene and preasphaltene) infurther forming oil products.
出处
《过程工程学报》
CAS
CSCD
北大核心
2002年第2期156-160,共5页
The Chinese Journal of Process Engineering
基金
National Natural Science Foundation of China (No. 29776015)
关键词
煤炭液化
浓缩
细分
co-liquefaction
coal
vitrinite
fusinite
sawdust
