摘要
测定了常压、 4 0℃下甲醇 /H2 O/H2 O2 /1,3,5 -三甲苯 /磷酸三辛酯五元系液液平衡数据 ,分别用UNIQUAC模型和NRTL模型对实验数据进行了关联 。
In this paper,the liquid-liquid equilibrium data of methanol/H 2O/H 2O 2/TMB/TOP are determined at 40℃ and at normal pressure.The experimental data are correlated with UNIQUAC and NRTL models,and the results are satisfactory.The relative mean deviation is less than 4%, and the relative maximal deviation is less than 8%.These parameters can be used to simulate the extraction process of the integrated process of epoxidation of propylene catalyzed by titanium silicalite (TS-1) and production of H 2O 2 by anthraquinone route.
出处
《化工学报》
EI
CAS
CSCD
北大核心
2002年第4期422-426,共5页
CIESC Journal
基金
国家自然科学基金 (No .2 9792 0 70 )
中国石化集团资助项目~~
关键词
含H2O2五元系
液-液相平衡
测定
关联
quinary of Containing H 2O 2,liquid-liquid equilibrium,determination,correlation
