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CSH凝胶结构的研究 被引量:2

Study on Structure of CSH Gel
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摘要 采用Ca(NO_3)_2和Na_2SiO_3合成了CSH凝胶。通过详尽的XRD分析,证实了CSH凝胶的层状结构,其层间距为11.6~14.2A;并以DSC和非蒸发水量的实验结果加以证实。对其中水的作用也进行了研究,实验结果有助于建立完整的水泥石结构模型。 CSH gel has been synthesised by the use of Ca(NO_3), and Na_2SiO_3. It is Proved that CSH gel has layer structure with basal spacing of 11. 6~14. 2A°using detailod XRD analysis. This conclu- sion has also been proved by the result of DSC ana1ysis and unevaporation water. The study on wa- ter in CSH gel has been done too. The results can help us to establish a complete structure modle of Hardend Cement Paste.
出处 《武汉工业大学学报》 CSCD 1991年第1期20-24,共5页
关键词 凝胶 CSH 层状结构 水泥 化学成分 CSH Layer structure
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参考文献1

  • 1R. F. Feldman,P. J. Sereda. A model for hydrated Portland cement paste as deduced from sorption-length change and mechanical properties[J] 1968,Matériaux et Constructions(6):509~520

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  • 1张文生,王宏霞,叶家元.水化硅酸钙的结构及其变化[J].硅酸盐学报,2005,33(1):63-68. 被引量:41
  • 2李建勇,唐尔焯.合成CSH凝胶在混凝土中的增强作用[J].混凝土,1995(6):16-22. 被引量:2
  • 3甘新平.CSH凝胶结构的探讨[J].硅酸盐学报,1996,24(6):629-634. 被引量:13
  • 4何赐全,杜海燕,孙家跃.无机纳米材料的水热合成及其衍生方法[J].化工新型材料,2007,35(10):19-21. 被引量:11
  • 5Beaudoin James J,Laila Raki,Rouhollah Alizadeh.A - (29)Si MAS NMR study of modified C-S-H nanostructures. Cement and Concrete Composites . 2009
  • 6AL-WAKEEL E I,EL-KORASHY S A.Effect of C-S-H-phase nuclei on building calcium silicate hy-drate phases. Cem Conr Composites . 1999
  • 7Scherer,GW.Structure and properties of gels. Cement and Concrete Research . 1999
  • 8Merlin,F,Lombois,H,Joly,S,Lequeux,N,Halary,JL,VanDamme.Cement-polymer and clay-polymer nano and meso composites: spotting the difference. Journal of Materials Chemistry . 2002
  • 9Karen L. Scriveber, Andre Nonat. Hydration of cementitious materials, present and future[ J 3. Cement and Concrete Research ,2011,41:651-665.
  • 10Sugama T, Kukacka L E. Effects of tobermorite and calcium silicate hydrate (I) crystals formed with in polymer concretes [ J ]. Journal of materials science, 1980,16 : 345 -354.

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