摘要
合成了钴(Ⅱ)、镍(Ⅱ)、铜(Ⅱ)和锌(Ⅱ)与水杨醛缩异烟肼Schiff碱的固态配合物.通过元素分析、红外光谱、紫外—可见光谱、摩尔电导、磁矩以及差热分析,对配合物进行了表征.配合物的组成可表示为M(HL)_2·xH_2O(M=Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)和Zu(Ⅱ),x=0-2).
N-isonicotinamidosalicylaldimine(H2L)complexes of cobalt(Ⅱ),Nickel (Ⅱ), Copper(Ⅱ) and Zinc(Ⅱ) have been synthesized and characterized by elementa analysis, IR and electronic spectra, molar conductance, magnetic moment and differential thermal analysis.The complexes have the compositions
M(HL)2·xH2o[M = Co(Ⅱ), Ni(Ⅱ),Cu(Ⅱ)a and Zn(Ⅱ), x=0-2] The bonding and stereochemistry of the complexes are discussed.
出处
《湖北大学学报（自然科学版）》
CAS
1989年第4期1-4,40,共5页
Journal of Hubei University：Natural Science
关键词
钴
镍
异烟肼
席夫碱
配合物
Isonicotinic hydrazide, Schiff base complex, Synthesis.
