摘要
本文合成了一个新的Schiff碱型大环配体“三氧二(?)”(L),及其C(?)(Ⅱ)、Ce(Ⅱ)、Ni(Ⅱ)、Zn(Ⅱ)、Cd(Ⅱ)、Ag(Ⅰ)的配合物,经红外光谱、电导、元素分析等推算了它们的组成并指认了谱带的归属.对Cu(Ⅱ)配合物进行了电子顺磁共振谱、光电子能谱分析.
A new Schiff's base macrocyclic compound (L) has been synthesized and characterized by elemental analyses, IR, MS.The complexes of Cu(Ⅱ), Co(Ⅱ). Ni(Ⅱ), Zn(Ⅱ), Cd(Ⅱ). Ag(Ⅰ) with L arc isolated. The complexes were characterized by elemental analyses, IR, electrical conductance. The ESR properties of Cu(Ⅱ) complex has been studied, and XPS of Cu(Ⅱ) complex indicates that the coordination ability of N in L is stronger than that of O.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1991年第3期253-256,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助的课题
关键词
配合物
西佛碱
大环
合成
Sc iiT s base twaeroeyelie eoinpoand, Cu Co Nl Za Cd Ag
