摘要
超临界水具有独特的性质 ,在理论和实际应用上都已经受到广泛的关注。超临界水的静态结构和动力学的研究是认识其性质的理论基础。氢键是静态结构研究的一个重要的内容 ,在实验上主要是通过谱学的方法如拉曼光谱、核磁共振 (NMR)、以及衍射分析等进行。动力学研究是探讨其作为反应介质的机理研究的基础。微波波谱法、NMR法。
Supercritical water has received much attention recently owing to its unique properties. The study of the static and dynamic structures of supercritical water is the basis to understand its properties. Raman spectroscopy, NMR and diffraction are important methods to study the static structures of supercritical water. The results of dynamics are the basis for study of reaction rate in supercritical water. Microwave spectrum, NMR and quasielastic incoherent neutron scattering have been adopted to study the dynamics of supercritical water.
出处
《光谱实验室》
CAS
CSCD
2002年第3期285-289,共5页
Chinese Journal of Spectroscopy Laboratory
基金
北京大学博士论文创新基金
国家自然科学基金 (No.4 0 0 730 2 5 )
国家重大自然科学基金 (No.10 0 32 0 4 0 )资助
