摘要
用二苄基二氯化锡与N ,N 二甲基荒酸钠反应合成了化合物 (PhCH2 ) 2 Sn[S2 CN(CH3) 2 ]2 ,通过X 射线确定了其晶体结构 ,晶胞参数为 :单斜晶系 ,空间群P2 1/n ,a =13.92 6 (5 ) ,b =9.832 (4) ,c =17.0 80 (7) ,β =10 3.5 41(6 )° ,V =2 2 73.7(15 ) 3,Z
The compound (PhCH 2) 2Sn[S 2CN(CH 3) 2] 2 was prepared by the reaction of dibenzyltin dichloride with sodium N,N dimethyldithiocarboxylate. Its crystal structure has been determined by X ray crystallography. It crystallizes in the monoclinic system, space group P2 1/n with a=13.926(5), b=9.832(4), c=17.080(7),β=103.541(6)°, V=2273.7(15) 3, and Z=4.
出处
《合成化学》
CAS
CSCD
2002年第2期126-130,共5页
Chinese Journal of Synthetic Chemistry
