摘要
氯的含氧酸氧化性强弱的规律是ClO^->ClO_3^->ClO_4^-,如何予以更圆满的解释呢,本文从两方面进行剖析,一方面从分子结构理论出发讨论其化学键形成的过程及特征;另一方面从化学反应中能量变化情况考虑,最后得到一致的结论。
The oxidation behaviour of oxychloric acid is in the sequence of ClO^->ClO_3^->ClO_4^-. A satisfactory explanation of this phenomenon is given over discussions in two different aspects. It is based on the theory of molecular structure and on the consideration of the forming of chemical bonds and their behaviours. Secondly, it takes into account the energy changes of the chemical reactions. A consistent result has then been obtained.
关键词
氯
含氧化酸
氧化性
杂化
杂化轨道
hybridized
hybridized orbit
spinning rearrangement
-coordination
-back coupling bond
symmetric matching
