摘要
本文利用文献〔1〕的实验数据,采交用正法对配合物的稳定常数和摩尔吸光系数进行了优选,结果使该配合物的参数指标(即标准差)由原来的0.03000下降为0.01790。计算表明只要知道参数的大致范围,经过几轮优选,最后能得到较好的估计值。
Orthogonal method is used to make an optimum selection of stability constants and molar absorptivity coefficients from literature experimental data. Results show that the parametric index (the standard deviation) of selected complexes has descended from the previous 0.3000 to 0.01790 Calculations indicate that when the approximate range of the parameters is known better estimate can be achieved by optimum selections.
出处
《黑龙江大学自然科学学报》
CAS
1989年第1期66-69,共4页
Journal of Natural Science of Heilongjiang University
关键词
硫氰酸钴
配合物
稳定常数
正交法
Stadilty constant, absorbance coefficient, orthogonal meJ I J'thod.'
