摘要
2-对羟基苯基 -5 ,1 0 ,1 5 ,2 0 -四苯基卟啉镍 ( )和 2 -邻羟基苯基 -5 ,1 0 ,1 5 ,2 0 -四苯基卟啉镍 ( ′)分别与丙烯酰氯反应 ,生成了 2 -对丙烯酰氧苯基 -5 ,1 0 ,1 5 ,2 0 -四苯基卟啉镍 ( )和 2 -邻丙烯酰氧苯基 -5 ,1 0 ,1 5 ,2 0 -四苯基卟啉镍 ( ′) ,在引发剂作用下 ,前者聚合生成了聚 2 -对丙烯酰氧苯基 -5 ,1 0 ,1 5 ,2 0 -四苯基卟啉镍( ) .通过元素分析、红外光谱、紫外 -可见光谱。
p propenoyloxyphenyl) 5,10,15,20 tetraphenylporphyrin nickel(Ⅱ) and 2 (o propenoyloxyphenyl) 5,10,15,20 tetraphenylporphyrin nickel(Ⅱ′) was synthesized from acryoyl chloride with 2 ( p hydroxyphenyl) 5,10,15,20 tetraphenylporphyrin nickel(Ⅰ) and 2 ( o hydroxyphenyl) 5,10,15,20 tetraphenylporphyrin nickel(Ⅰ′) correspondingly. Compound (Ⅱ) was further polymerized to 2 ( p propenoyloxyphenyl) 5,10,15,20 tetraphenylporphyrin nickel(Ⅲ) in the presence of initiator. Their chemical structures were identified by NMR, UV Vis, IR and MS spectra, as well as elemental analysis.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2002年第2期173-175,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金 (批准号 :2 9872 0 33)资助
