摘要
杂多化合物还原时,电子占据较低的空轨道,这个轨道的能量决定电子亲合能(氧化—还原电位),且钨的杂多化合物还原的双电子产物是抗磁性的.解释了 P_2W_(18)和 P_2M_(018)结构阴离子在电化学还原中的区别.
When a heteropolycompound is reduced,the electrons occupy the lower unoccupied orbital,and the energy of which decides the electron affinity(redox potential)of the com pound.The dielectronic reduction products of hetropolycompound of tungsten are diamag netic,and the differences of P_2W_(18)and P_2M_(018)Structural anions in electrochemical reduc tion,have been explained.
出处
《沈阳化工学院学报》
1991年第3期184-188,共5页
Journal of Shenyang Institute of Chemical Technolgy
