摘要
在 2 5℃和进料中含水条件下 ,考察了由 Na2 CO3 ,( NH4) 2 CO3 ,Na OH和 NH4OH等 4种沉淀剂制备的Au/Zn O催化剂上 CO氧化活性和稳定性 .结果表明 ,沉淀剂影响 Au/Zn O催化剂的前体组成、金粒子和Zn O粒子大小、比表面积及 CO氧化性能 .由 NH4OH制备的 Au/Zn O催化剂活性和稳定性较差 ,CO转化率只有 1 5 % ;由其它 3种沉淀剂制备的 Au/Zn O催化剂的 CO氧化活性和稳定性明显改善 ,可至少连续反应1 1 0 0 h,且保持 CO完全氧化 ,其中 Na2 CO3 是最佳沉淀剂 .在反应过程中反应气氛可引起金粒子的聚集及在催化剂表面生成新的碱式碳酸锌物相 .
Various Au/ZnO catalysts were prepared by a coprecipitation method with four kinds of precipitants, Na 2CO 3, (NH 4) 2CO 3, NaOH and NH 4OH, and the catalytic performance of CO oxidation at an ambient temperature and humidity were studied. It was found that the precipitants play an important role for the Au/ZnO catalyst structure, such as the precursors, the particle size of ZnO and metallic gold and the BET surface area of Au/ZnO catalysts. The sample prepared by using NH 4OH as precipitant exhibited a lower activity and poorer stability, while the Au/ZnO catalysts prepared by other three precipitants can maintain CO completely oxidized to CO 2 for at least 1 100 h. The feed gas mixture can result in sintering of metallic gold and accumulation of carbonate like species on the surface of Au/ZnO catalysts during the CO oxidation process. The stability is related to the rate of gold sintering and the amount of hydrozincite formed on the catalyst surface.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2001年第11期1873-1876,共4页
Chemical Journal of Chinese Universities
基金
太原煤转化国家重点实验室
吉林大学创新基金
国家自然科学基金 (批准号 :2 0 0 7316 7)资助
