C_(60)Cl_6与蒽环加成反应研究

STUDY OF CYCLOADDITION OF ANTHRACENE WITH C_( 60)Cl_6

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摘要研究了C60 Cl6与蒽的环加成反应 .经高压液相色谱 (HPLC)分离和1HNMR检测 ,发现反应产物主要为C60 蒽的单加成产物和C60 ,同时有副产物蒽醌 .说明在该反应条件下 ,C60 Cl6易消去氯而转化为C60 . Cycloaddition of anthracene with C 60Cl 6 was studied. The high pressure liquid chromatography (HPLC) analyses showed the products are composed of monoadduct of C 60 and anthracene, C 60 and anthraquinone. Each compound was characterized by 1HNMR spectroscopy. The results indicate that C 60Cl 6 is easy to be decomposed to C 60 under this reaction condition.

作者张辉张新明魏先文

机构地区黄山高等专科学校化学系安徽师范大学化学与材料科学学院

出处《安徽师范大学学报（自然科学版）》 CAS 2001年第4期325-326,共2页 Journal of Anhui Normal University(Natural Science)

基金安徽省自然科学基金 ( 4 5 12 2 )

关键词 C60Cl6 蒽环加成反应高压液相色谱富勒烯族化合物 C 60Cl 6 anthracene cycloaddition high pressure liquid chromatography

分类号 O635.1 [理学—高分子化学] O625.154 [理学—有机化学]

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1孙健,何月珍.C_(60)Cl_6纳米管的合成及其表征[J].池州学院学报,2011,25(3):34-35.

安徽师范大学学报（自然科学版）

2001年第4期

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C_(60)Cl_6与蒽环加成反应研究

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