摘要
本文用气液色谱法研究了Ni[(C_8H_(17)O)_2PS_2]_2与四氢呋喃加合反应的热力学性质。测定了333-363K范围内加合反应的平衡常数,用最小二乘法求得反应的△H和△S。加合反应的平衡常数可以用下列经验公式描述: lgK=-4.2787+1402.
The GLC study on the thermodynamic properties of adduct formation reactions between Ni[(C_8H_(17)O)_2PS_2]_2 and tetrahydrofuran was reported. Thermodynamic parameters, -△H and -△S, were determined by least square method. The equilibrium constants of the reactions were determined between 333 to 363K and fit the empirical equationlgK=-4.2787+1402.3/T
出处
《南京师大学报（自然科学版）》
CAS
CSCD
1991年第1期48-51,共4页
Journal of Nanjing Normal University(Natural Science Edition)
关键词
四氢呋喃
硫代磷酸酯
加合反应
Gas-Liquid chromatography, Acid- base adduct, Thermodynamic parameters, Dialkyldithiophosphate, Tetrahydrofuran.
