摘要
报道了以苯肼和 3 甲基 2 丁酮为原料首先合成 2 ,3 ,3 三甲基吲哚 ,吲哚再与碘乙烷亲核取代 ,碱化得费舍尔碱 ,最后与 1 亚硝基 2 萘酚作用合成N 乙基 [3 ,3 二甲基螺吲哚啉萘并恶嗪 ](简称螺恶嗪 )的全过程 。
In this work, 2,3,3 trimethyl indole was first produced from phenyl hydrazine and isopropyl methyl ketone . Then indole was made to react with iodine ethane, and the product of the reaction was alkalized into Fisher alkali. Finally, N ethey[3,3 dimethyl spiralindoline naphthoxazine](spiral oxazine)was synthesized by the addition of 1 nitroso 2 naphthol also,the photochromic mechanism of the substance and its photochromic phenomenon in ethanol were studied.
基金
吉林省科委自然科学基金资助项目 (吉科合字第 2 0 0 10 5 13号 )
