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磺化聚苯乙烯镧离子型聚合物的稀溶液性质 被引量:2

Solution Property of Sulfonated Polystyrene Lanthanum Ionomers
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摘要 The viscosity behavior of the sulfonated polystyrene lanthanum ionomers(SPS La) has been investigated in comparison with the sodium and zinc ionomers in polar solvents. The results indicated that the SPS La with the same sulfonation degree exhibited higher reduced viscosity and intrinsic viscosity when the polarity of the solvents was high. The lower the sulfonation degree of SPS La, the higher the reduced viscosity of SPS La, especially in case of estremely dilute dolutions. The order of the reduced viscosity and the polyelectrolyte effect tendency are:SPS Na>SPS Zn> SPS>SPS La . The viscosity behavior of the sulfonated polystyrene lanthanum ionomers(SPS La) has been investigated in comparison with the sodium and zinc ionomers in polar solvents. The results indicated that the SPS La with the same sulfonation degree exhibited higher reduced viscosity and intrinsic viscosity when the polarity of the solvents was high. The lower the sulfonation degree of SPS La, the higher the reduced viscosity of SPS La, especially in case of estremely dilute dolutions. The order of the reduced viscosity and the polyelectrolyte effect tendency are:SPS Na>SPS Zn> SPS>SPS La .
出处 《应用化学》 CAS CSCD 北大核心 2001年第8期667-669,共3页 Chinese Journal of Applied Chemistry
基金 广东省自然科学基金资助项目 ( 96 0 0 0 8)
关键词 磺化聚苯乙烯 镧离子型 聚合物 聚电解质 比浓粘度 稀溶液 性质 sulfonated polystyrene lanthanum,ionomer,polyelectrolyte effect,reduced viscosity
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