摘要
本文假定ZnWO4:Cr^3+具有变形的八面体结构,属于D2^*群。采用D^h点群表象简化准时角型强场方案,导出了d^3-D2^*强场能量矩阵。与实验资料拟合,算出了^4F态的精细光谱,得到了13条谱线,理论结果与实验吻合。
The ZnWO4:C_r~(3+) was assumed to have structure of the low symmetry belonging to the D2 group by this paper. By means of a representation of the Oh-group and using strong field design. An Calculation the eigenvalues of the strong field energy matrix was given to the fine structure of the spin- allowed bands of the basic state 4F. The results are agreement with experiments.