摘要
介绍了烯烃催化羰化原理、反应历程以及对催化剂的要求和反应条件,依据空间效应和电子授受原理阐述了不同烯烃羰化和双羰化的难易程度和产物分布,文中指出选用高活性、高选择性的催化剂有可能在温和条件下合成系列的有机羧酸(酯)和醇,从而为精细石油化工合成开拓新途径。
The mechanism, catalyst required and reaction condition for catalytic corbonylation of olefines were described. The degree of reaction difficulty and yields distribution of various olefines were discussed on the basis of spatial effect as well as principle of electron donation and acception. While an optimized catalyst with high activity and selectivity is used ,it is possible to synthesizing a series of carboxylic acids(or esters) or alcohols under mild condition, thus a new way for fine chemical synthseis can be developed.
出处
《精细石油化工》
CAS
CSCD
1991年第1期11-14,共4页
Speciality Petrochemicals
关键词
烯烃
羰化
羧酸
羧酸酯
醇
Catalytic Carbonylation of Olefines
Carboxylic Acid
Carboxylic Ester
Alcohol
