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原位傅里叶变换红外光谱跟踪等规聚丙烯在升温过程中的构象变化 被引量:10

In-situ FTIR Spectroscopic Study on the Conformational Change of Isotactic Polypropylene upon Heating
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摘要 The experimental data obtained from fast heating FTIR spectroscopy have confirmed that a conformational change occurs at about 135 ℃ for semicrystalline iPP. Based on the results of density and WAXD measurements, it can be inferred that the conformational change occurring at 135 ℃ comes from the disordering of helical sequences in non crystalline phase, which is further corroborated by the FTIR study on the chloride polypropylene. The experimental data obtained from fast heating FTIR spectroscopy have confirmed that a conformational change occurs at about 135 ℃ for semicrystalline iPP. Based on the results of density and WAXD measurements, it can be inferred that the conformational change occurring at 135 ℃ comes from the disordering of helical sequences in non crystalline phase, which is further corroborated by the FTIR study on the chloride polypropylene.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第8期1425-1427,共3页 Chemical Journal of Chinese Universities
基金 国家重点基础研究专项经费 (批准号 :G19990 6 480 0 )资助 Bruker公司提供了部分资助
关键词 等规聚丙烯 原位傅里叶变换 红外光谱 构象 升温过程 结构 Isotactic polypropylene FTIR spectroscopy Conformation
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参考文献4

  • 1Zhu X Y,Colloid Polym Sci,2001年,279卷,292页
  • 2Zhu X Y,Macromol Chem Phys,2001年,202卷,1109页
  • 3Zhu X Y,Macromol Rapid Commun,2000年,21卷,354页
  • 4徐端夫,高分子学报,1981年,5卷,350页

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