摘要
A Cu? complex with mix ligands [Cu(HIm)2(PPh3)2](BF4) was synthesized and characterized by elemental analysis, IR spectroscopy and X ray diffraction crystallography. The crystal belongs to monoclinic system and P21/c space group, with cell parameters, a=1.2836(3)nm, b=1.5089(3)nm, c=2.0661(4)nm, α=90°, β=101.464(4)°,γ=90°, V=3.9219(13)nm3, Z=4 and Dc=1.374mg·m-3. The Cu? is coordinated by two P atoms from triphenylphosphine and two N atoms from imidazole to form the distorted tetrahedral geometry.
A Cu? complex with mix ligands [Cu(HIm)2(PPh3)2](BF4) was synthesized and characterized by elemental analysis, IR spectroscopy and X ray diffraction crystallography. The crystal belongs to monoclinic system and P21/c space group, with cell parameters, a=1.2836(3)nm, b=1.5089(3)nm, c=2.0661(4)nm, α=90°, β=101.464(4)°,γ=90°, V=3.9219(13)nm3, Z=4 and Dc=1.374mg·m-3. The Cu? is coordinated by two P atoms from triphenylphosphine and two N atoms from imidazole to form the distorted tetrahedral geometry.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2001年第4期593-596,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.29901004)
广东省自然科学基金资助项目(No.000779)
关键词
铜(Ⅰ)配合物
咪唑
三苯基膦
晶体结构
copper(Ⅰ)complex
imidazole
triphenylphosphine
crystal structure
