摘要
本文讨论配位吸附准可逆波测定标准电极反应速率常数(k(?))和转移系数(α)的理论与方法,实验结果证实,方法简便,结果正确.
It is discussed that the theory of adsorptive-complex wave for the electrode process controlled simultaneously by multiple factors such as adsorption, diffusion, charge transfer rate and so on. The general equations for the reversible, quasi-reversible, irreversible adsorptive-complex waves include normal polarographic wave equation, the first derivative polarographic wave equation and the second derivative polarographic wave equation is also investigated. The theoretical conclusions are in good agreement with experimental data for the reduction of Pb(Ⅱ) in the presence of oxine.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1991年第5期488-492,共5页
Acta Chimica Sinica
基金
国家自然科学基金资助的课题
