摘要
该文根据以静电作用、取向作用、诱导作用和色散作用为基础的分子间相互作用力,对AgCl、AgBr、AgI、AgN_3、AgSCN及AgAc等6种难溶盐在MeOH、EtOH、MeCN、DMF、DMAC、DMSO和HCONH_2等7种非水溶剂中的离解平衡常数K_(SP)进行了理论计算,计算结果与文献值吻合较好。
This article is a theoretical calculation of activity product ofseveral silver salts in a number of nonaqueous solvents. According to the in-teraction force theory which based on the interaction energy of electrostatic,orientation, induction & dispersion. The accordance between the calculatedvalues of pK_(SP) and those from literatures is good.
关键词
非水溶液
难溶盐
溶度积
离解平衡
non-aqueous solution
solubility product
interactions
