期刊文献+

马来酸酐(MA)接枝聚砜聚合物对原位复合体系的增容改性研究 被引量:1

Compatibilizing Effect of Maleic Anhydride Graft Polysulone on Blends of Polysulfone and Thermotropic Liquid Crystalline Polymer
在线阅读 下载PDF
导出
摘要 针对聚矾 /热致液晶聚合物 ( PSF/ TLCP)原位复合材料相容性差的问题 ,运用分子设计思想合成了一种马来酰基接枝聚砜增容剂。将这种增容剂用于 PSF/ TLCP原位复合材料 ,对其增容效果进行了综合分析。DSC分析及 SEM分析结果表明 ,少量的这种增容剂使 TLCP在基体中分散较均匀 ,粒径减小。力学性能测定结果表明 ,加入该类增容剂后原位复合体系的拉伸强度、弯曲强度增加了约 7% ,拉伸摸量也增加了近 9% We had developed Polysulfone(PSF)/Thermotropic Liquid Crystalline Polymer(TLCP) blends. But the poor compatibility of PSF/TLCP blends had limited their use in China. We prepared a compatibilizer, Maleic Anhydride Graft Polysulone, for improving the compatibility of PSF/TLCP blends. Results of differential scanning calorimetry(DSC) and scanning electron microscopy(SEM) showed that by adding a small amount of compatibilizer we could improve the distribution of TLCP fiber in polysulfone matrix and decrease the diameter of TLCP fiber. Compared to uncompatibilzed blends, the bending strength and tensile strength of compatibilized PSF/TLCP blends were higher by 6.4% and 6.6% respectively, and tensile modulus was higher by 9%.
出处 《西北工业大学学报》 EI CAS CSCD 北大核心 2001年第2期173-176,共4页 Journal of Northwestern Polytechnical University
关键词 原位复合材料 相容性 增容剂 PSF/TLCP 聚砜 马来酰基 blend, compatibility, compatibilizer, polysulfone
  • 相关文献

参考文献1

  • 1张铸勇,精细有机合成单元反应,1992年

同被引文献18

  • 1倪玉山,王云辉,李滨耀,董德文,关荐伊.热致液晶高分子聚酯醚砜及其共混物流变行为的研究[J].高分子材料科学与工程,1994,10(5):87-90. 被引量:3
  • 2Chinsirikul W, Hsu T C, Harrison I R. Liquid crystalline polymer(LCP) reinforced polyethylene blend blown film:Effects of counter-rotating die on fiber orientation and film properties. Polymer Eng Sci, 1996, 36 (22):2 078-2 083
  • 3Tjong S C, Jiang GW. Mechanical performance of ternary in situ poly (aerylonitrile-butadiene-styrene)/liquid crystalline polymer composites. J Appl Polym Sci, I999, 74 (2):2 274-2 282
  • 4Lin Q H, Yee A F. Maehanical properties of in situ composites based on polyearbonate and a liquid crystalline polymer.Polymer, I994, 35:3 463-3 469
  • 5Sata H, Kimura T, Ogawa S, et al. Magnetic orientation of poly (ethylene-2, 6-naphthalate). Polymer, I996, 37(10): 1879-1882
  • 6Benicewicz B C, Smith M E, Earls J D, et al. Magnetic field orientation of liquid crystalline epoxy thermosets.Maeromoleeules, 1998, 31(15):4 730-4 738
  • 7Hidetashi Ezure, Tsunehisa Kimura, Shintaro Ogawa, etal. Magnetic oriention of isotactic polystyrene. Macromolecules, I997, 30(12): 3 600-3 605
  • 8Rodin Yu P, Mochanov Yu M. Effect of conformational changes caused by a uniform constant magnetic field on the curing of epoxy resin. Mekh Kompoz Mater, 1998, 24(3): 497-506
  • 9Kawai T, Kimura T. Magnetic orientation of isotactic polypropylene. Polymer, 2000,41( 1 ) :155-159
  • 10Sata H, Kimura T, Ogawa S, et al. Magnetic orientation of poly ( ethylene-2, 6-naphthalate) during crystallization from melt. Polymer, 1998, 39 (25) : 6 325-6 330

引证文献1

二级引证文献1

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部