摘要
本文研究了叔十二烷基硫醇引发甲基丙烯酸甲酯与丙烯腈共聚在三种不同溶剂中反应的动力学有关问题.发现硫醇引发该共聚反应中,聚合反应速率随单体中甲基丙烯酸甲酯的组分增大而提高,及与溶剂的极性成正比关系.
This paper studies problems of lunatics about polymerization reaction of methyl methacrylate with acrylonitrile initiated by 2-methyl-2-undecanetlliol in three different solvents. Describes that the rate of the copolymerization increases with the increase of the value of methyl methacrylate in monone rand the polar of the solvent .
关键词
硫酸
引发剂
MMA
丙烯腈
共聚
electron-transfer complex
polar of the solent
