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含稀土铽(Ⅲ)配合物透明树脂的制备及性能研究 被引量:23

The Preparation and Property Studies of Transparent Resins Containing Rare Earth Terbium(Ⅲ) Complex
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摘要 The binary and ternary rare earth terbium(Ⅲ) complexes were introduced into the styrene/ α methylacrylic acid copolymerization system, and some optical resins that possess a high transparency in visible light region were obtained. The study of the optical property showed that they have good luminescent properties such as a high luminous intensity and a long luminous lifetime. In addition, we investigated the relationship among the transparency, the luminescent property of the copolymer, and the content of the components in the polymeric system. The results indicated that the optical resins can provide a relatively stable environment for composite rare earth complexes, which is good to exhibit the luminescent properties of rare earth complexes. At the same time, the rare earth complexes can offer the transparent resin a novel function. The binary and ternary rare earth terbium(Ⅲ) complexes were introduced into the styrene/ α methylacrylic acid copolymerization system, and some optical resins that possess a high transparency in visible light region were obtained. The study of the optical property showed that they have good luminescent properties such as a high luminous intensity and a long luminous lifetime. In addition, we investigated the relationship among the transparency, the luminescent property of the copolymer, and the content of the components in the polymeric system. The results indicated that the optical resins can provide a relatively stable environment for composite rare earth complexes, which is good to exhibit the luminescent properties of rare earth complexes. At the same time, the rare earth complexes can offer the transparent resin a novel function.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第4期695-697,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金! (批准号 :2 992 5 412 )资助
关键词 透明树脂 光学性质 铽(Ⅲ)配合物 苯乙烯 甲基丙烯酸 共聚体 Transparent resin Rare earth complex Optical property
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