摘要
激光拉曼光谱作为研究电极 /溶液界面的结构和性能的重要方法 ,在分子水平上深入研究电化学界面结构、吸附和反应等基础问题并应用于电催化、腐蚀和电镀等领域 .从方法学的角度出发 ,结合探讨检测灵敏度、光谱分辨率、时间分辨率和空间分辨率以及相关的联用技术等方面的问题 ,综述了近年来拉曼光谱研究电化学界面的主要进展 .
As an important method in investigating the detailed structure and dynamic process of the electrode/electrolyte interface, laser Raman spectroscopy is able to study at molecular level the systems of fundamental interest such as the electrochemical interfacial structure, the adsorption and reaction and those of application interest such as the electrocatalysis, corrosion and electroplating etc. Based on the work of our group, the progress of laser Raman spectroscopy in the study of electrochemical interfaces is overviewed in terms of the detection sensitivity, spectral resolution, temporal resolution, spatial resolution and the related hyphenated techniques.
出处
《厦门大学学报（自然科学版）》
CAS
CSCD
北大核心
2001年第2期434-447,共14页
Journal of Xiamen University：Natural Science
基金
国家自然科学基金!(2 96 2 530 6
2 98330 6 0
2 990 30 0 9)
教育部重点!(99177)资助项目
