摘要
The insertion of CS_2 into M--S bonds has been studied. CS_2 can be inserted intopart of a set of Cu--S or Ag--S bonds in polynuclear compounds, forming clusterswith thiolate (RS^-) and trithiocarbonate (RSCS_2^-) mixed ligands. This is anew way to prepare clusters with sulphur-containing ligands, In 1986, Chadha reportedthe first cluster complex Cu_8(S_2CSMe_2Et)_4(SCMe_2Et)_4 prepared by insertionof CS_2 into Cu--S bonds. In recent years, we have obtained several clusters
