摘要
[Cd(NH2CSNHNH2) Br2]· H2O is a new nonlinear optical organometallic complex, and the single crystal structural analysis has been carried out by X-ray diffraction method. According to the model of the second order polarizabili-ty vector, the second order polarizability of one dimensional doubling frequency group of the title compound was calculated using the structural data and the second harmonic relative intensity I2ω/I2ω,KDP.
[Cd(NH2CSNHNH2) Br2]· H2O is a new nonlinear optical organometallic complex, and the single crystal structural analysis has been carried out by X-ray diffraction method. According to the model of the second order polarizabili-ty vector, the second order polarizability of one dimensional doubling frequency group of the title compound was calculated using the structural data and the second harmonic relative intensity I2ω/I2ω,KDP.
基金
The Project supported by National Natural Sciences Foundation of China