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CRYSTAL STRUCTURE OF MIXED-METAL CLUSTER (η~5-C_5H_5)_2W_2Fe_2(μ_3-S)_2(CO)_8

CRYSTAL STRUCTURE OF MIXED-METAL CLUSTER (η~5-C_5H_5)_2W_2Fe_2(μ_3-S)_2(CO)_8

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摘要 (η5-C5H5)W2Fe2(μ3-S)2(CO)8,Mr = 897. 80,monoclinic,C2/c,a= 18. 019 (2),b = 8. 330(1),c= 16. 043(2) A ,β= 114. 30(1)°,v = 2194. 7(6)A3,z= 4, Dx = 2. 717g/cm3, A(MoKa) = 0. 71037 A , μ= 122. 01cm-1, F (000) = 1656, T = 295K,R=0.056,Rw = 0. 059 for 1250 observed reflections. The crystals of the title compound are isomorphous with the analog (η5-C5H5)2Mo2Fe2(μ3-S)2(CO)8. (η5-C5H5)W2Fe2(μ3-S)2(CO)8,Mr = 897. 80,monoclinic,C2/c,a= 18. 019 (2),b = 8. 330(1),c= 16. 043(2) A ,β= 114. 30(1)°,v = 2194. 7(6)A3,z= 4, Dx = 2. 717g/cm3, A(MoKa) = 0. 71037 A , μ= 122. 01cm-1, F (000) = 1656, T = 295K,R=0.056,Rw = 0. 059 for 1250 observed reflections. The crystals of the title compound are isomorphous with the analog (η5-C5H5)2Mo2Fe2(μ3-S)2(CO)8.

作者郑碧仙黄锦顺等

机构地区 FuzhoulaboratoryofStructuralChemistry FuzhoulaboratoryofStructuralC

出处《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1991年第3期231-233,共3页 结构化学（英文）

关键词晶体结构原子簇形化合物钨铁硫羰基配合物

分类号 O641.4 [理学—物理化学] O76 [理学—晶体学]

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参考文献4

1Cai Qingrong，结构化学，1989年，8卷，1期，65页
2Yang Xiaoguang，Sci Chin B，1987年，12期，1266页
3Cai Qingrong，结构化学，1987年，6卷，2期，110页
4Yang Xiaoguang，结构化学，1985年，4卷，50页

1胡宁海,徐吉庆,等.CRYSTAL STRUCTURE OF Fe_4S_4[SC(CH_3)_3]_4[(C_4H_9)_4N]_2[J].Chinese Journal of Structural Chemistry,1991,10(2):117-120.
2金祥林,倪海洪,等.SYNTHESIS AND CRYSTAL STRUCTURE OF A MOLYBDENUM-COPPER-SULFUR CLUSTER COMPLEX WITH DITHIOBENZOATE LIGAND [Bu_4N]_2[MoCu_2S_4(C_6H_5CS_2)_2][J].Chinese Journal of Structural Chemistry,1992,11(1):73-77.
3郑发鲲,余秀芬.Studies on the V—Cu—S Heterometallic Cluster Compounds （2）.Crystal Str[J].Chinese Journal of Structural Chemistry,1994,13(5):397-401. 被引量：3
4郎建平,郁开北,等.STUDIES ON THE SOLID STATE REACTIONS OF COORDINATION COM POUNDS(ⅩⅩⅩⅩⅥ)——Solid State Synthesis and Crystal Structure of Cluster Compound{Ag_3WS_3Br}(PPh_3)3S·H_2O[J].Chinese Journal of Structural Chemistry,1992,11(4):274-278.
5刘晃,徐立,等.Synthesis and Structure of Propionate-bridged Mixed-metal Cluster Compound: MoW_2O_2 (O_2CC_2H_5)_6 (H_2O)_3 ZnBr_4·4H_2O[J].Chinese Journal of Structural Chemistry,1994,13(1):52-55. 被引量：3
6蔡钦荣,郑碧仙.CRYSTAL STRUCTURE OF MIXED-METAL CLUSTER(η~5-C_5H_5)_2Mo_2Fe_2(μ3-S)_2(μ-CO)_2(CO)_6[J].Chinese Journal of Structural Chemistry,1989,8(1):65-67.
7陈秋华,卢绍芳,等.Synthesis and Crystal Structure of Mixed Mo-W Cubane-type Cluster Compound [Mo_2W_2S_4 (μ-OAc)_2 (dtp)_3(dtpH)]·CH_2Cl_2[J].Chinese Journal of Structural Chemistry,1995,14(2):97-101.
8洪茂椿,刘汉钦.Electron-rich Polynuclear Transition Metal Clusters:Ⅱ.Synthetic and Structural Studies of Some Polynuclear Coinage Metal Cluster Compounds[J].Chinese Journal of Structural Chemistry,1994,13(4):316-323.
9陈文章,陈金海,等.STUDY OF ELECTROCHEMISTRY OF TETRANUCLEAR MOLYB-DENUM CLUSTER COMPOUND [Mo_4S_4(μ-dtp)_2(dtp)_4][J].Chinese Journal of Structural Chemistry,1992,11(4):283-285.
10刘启旺,黄锦顺,等.STRUCTURAL STUDY ON HETEROCYCLIC CARBENE-CONTAIN-ING IRON CARBONYL CLUSTER-STRUCTURES OF Fe_3(CO)_8-[CNH C(CH)_4CNH](μ_3-S)_2[J].Chinese Journal of Structural Chemistry,1992,11(2):104-108.

Chinese Journal of Structural Chemistry

1991年第3期

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