摘要
n-Bu )_4N]_2 [Mo_4O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2 ] crystallizes in the monoclinic, space group P21/c, a= 10. 926 (6) , b= 17. 861 (7) . c= 16. 258 (7) ,β=91. 16(4)°, V= 3172 (2) ￣3, Z = 2, M_r = 1407. 0, D_c =1. 473 g/cm￣3 , μ= 0. 814mm￣(-1), F(000) = 1448. T= 298K , final R= 0. 043 and R_w= 0. 058 for 3291 observed reflections. The structure of the complex consists of two (n-Bu)_4N￣+ cations and one [Mo_4 O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2]￣(2-) anion having crystallographic C_i symmetry, with a tetranuclear core of [Mo_4 O_(10)(OCH_3 )_2]￣(2+) .
n-Bu )_4N]_2 [Mo_4O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2 ] crystallizes in the monoclinic, space group P21/c, a= 10. 926 (6) , b= 17. 861 (7) . c= 16. 258 (7) ,β=91. 16(4)°, V= 3172 (2) ￣3, Z = 2, M_r = 1407. 0, D_c =1. 473 g/cm￣3 , μ= 0. 814mm￣(-1), F(000) = 1448. T= 298K , final R= 0. 043 and R_w= 0. 058 for 3291 observed reflections. The structure of the complex consists of two (n-Bu)_4N￣+ cations and one [Mo_4 O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2]￣(2-) anion having crystallographic C_i symmetry, with a tetranuclear core of [Mo_4 O_(10)(OCH_3 )_2]￣(2+) .
