摘要
以丙烯酸酯类单体为原料，通过溶液聚合，合成了一种溶剂型汽车膜用单组份丙烯酸酯压敏胶。并对影响压敏胶性能的诸多因素，如单体浓度、溶剂、聚合反应温度、反应时间等进行了研究，结果表明：甲苯、乙酸乙酯、甲醇比例为6砄2砄2，单体含量40％，反应温度80℃，反应时间6～7 h，合成的丙烯酸酯压敏胶粘剂综合性能较好， DSC测试玻璃化温度Tg：-32.48℃，数均分子量Mn：122189，重均分子量Mw：556863。
Solvent-based Polyacrylate PSA for automotive film was synthesized by solution polymerization method.The effects of solvent tape , bath temperature , monomer content and holding time on the properties of PSA were studied.The results indicated that when TOL/Ea/Ma was 6：2：2 , bath temperature was 80℃, monomer content was 40%, and holding time was 6-7 h, and the prepared PSA had good comprehensive.The results of DSC showed that the Tg of PSA was -32.48 ℃, Mn：122 189, and Mw：556 863.
出处
《广州化工》
CAS
2014年第11期86-88,102,共4页
GuangZhou Chemical Industry
关键词
汽车膜
丙烯酸酯
压敏胶
溶液聚合
automotive film
acrylate
pressure sensitive adhesive （PSA）
solution polymerization method
