摘要
A new photosensitive charge transfer complex has been synthesized based on phosphomolybdic acid and α-phridylazo-β-naphthol and characterized by elemental analysis, IR spectrum, UV spectrum, The resalts of IR spectra showed that the coordinating atom of α-phridylazo- β-naphthol was oxygen of C-O bond. The organic ligands do not coordinat5e with heteropolyanions, but with Protons in heteropoly acid by coordination bond. Photochromism studies show that the electron transfer takes place from the organic molecules to the heteropolyanions.
A new photosensitive charge transfer complex has been synthesized based on phosphomolybdic acid and α-phridylazo-β-naphthol and characterized by elemental analysis, IR spectrum, UV spectrum, The resalts of IR spectra showed that the coordinating atom of α-phridylazo- β-naphthol was oxygen of C-O bond. The organic ligands do not coordinat5e with heteropolyanions, but with Protons in heteropoly acid by coordination bond. Photochromism studies show that the electron transfer takes place from the organic molecules to the heteropolyanions.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2001年第2期289-291,共3页
Chinese Journal of Inorganic Chemistry
基金
湖北省重点科技攻关项目!(No.992PO321)
