摘要
合成了一系列丙烯酰胺 -丙烯酸十四酯共聚物镍配合物 ;采用 ESR、 XPS、 IR、 DTA- TG和电导率法 ,研究了其中存在的配位结构 ,通过镍配合物催化甲基丙烯酸甲酯的聚合反应 ,考察了它们的催化性能 。
A series of acrylamide tetradecyl acrylate copolymer nickel complexes were synthesized. Using ESR, XPS, IR, DTA TG fechniques and specific conductivity measurement, the coordination units in the complexes were studied. Their catalytic properties in polymerization of MMA were also examined. Experimental results reveal that these complexes possess high catalytic activity and low pollution.
出处
《分子催化》
EI
CAS
CSCD
北大核心
2001年第1期61-65,共5页
Journal of Molecular Catalysis(China)
基金
福建省自然科学基金资助项目! (B970 12 ) .
