期刊文献+

快速固化酚醛树脂胶黏剂的研制 被引量:4

Study on Fast-Curing Phenol-Formaldehyde Resin Adhesive
原文传递
导出
摘要 以缩短酚醛树脂固化时间为目的,使用纳米氧化铝为催化剂,丁腈橡胶为增韧剂,AlCl3络合物为固化促进剂,制备了一种能够快速固化的酚醛树脂胶黏剂。通过固化时间、DSC、TG和力学性能等测试,结果表明,当加入15%丁腈橡胶和2%AlCl3络合物时,酚醛树脂胶黏剂的增韧效果和固化速度均为最佳,可在180℃下20min内实现快速固化,同时具有优异的耐热性能和力学性能。 To reduce the curing time of phenol-formaldehyde resin, using nano-alumina as catalyst, nitrile rubber as toughening agent and AlCl3 complex compounds as curing accelerator, then the fast-curing phenol-formaldehyde resin adhesive was prepared. By the results of curing time, DSC, TG and mechanical properties test, it was shown that when added 15% nitrile rubber and 2% AlCl3 complex compounds, the fast-curing phenol-formaldehyde resin adhesive could be cured with excellent heat resistance and mechanical properties at 180℃within 20min.
出处 《化学与粘合》 CAS 2014年第3期181-183,187,共4页 Chemistry and Adhesion
关键词 酚醛树脂 固化促进剂 快速固化 Phenol-formaldehyde resin adhesive curing accelerator fast-curing
  • 相关文献

参考文献4

二级参考文献22

  • 1伏传龙,鲁钢,魏无际,敖文亮,朱文元.低游离醛高羟甲基含量酚醛树脂的合成[J].热固性树脂,2004,19(5):17-19. 被引量:13
  • 2张云云,张一帆,何良佳.pH值对酚醛甲阶树脂固化速率的影响[J].东北林业大学学报,2006,34(6):80-81. 被引量:5
  • 3李和平.胶粘剂生产原理与技术[M].北京:化学工业出版社,2009:130-207.
  • 4Bender H L,Farnham A G,Guyer J W,et al.Purified chemicals and resins from Phenol and Formaldehyde[J].Ind Engng Chem,1952,44(6):1619-1629.
  • 5Fraser D A,Hall R W,Raum A L J.Preparation of 'high-ortho'novolak resins I:Metal ion catalysis and orientation effect[J].J Appl Chem,1957,12(7):676-89.
  • 6He Liangjia,Han Renlu,Zhang Yifan.Cure characteristics of phenol-formaldehyde resin catalyzed with Ba(OH)2[J].Journal of Adhesion Science and Technology,2009,23(12):1639-1645.
  • 7赵临五,中国林学会木材工业分会论文集.12,1996年,34页
  • 8王凯,中国林学会木材工业分会论文集.10,1995年,1页
  • 9MANFREDI L B, DE LAOSA O, FERNANDEZ G N, et al . Structure properties relationship for resols with different formalde- hyde phenol molar ratio[ J] . Polymer, 1999, 40(13): 3 867-3 875.
  • 10LUUKKO P, ALVILA L, HOLOPAINEN T, et al. Effect of alkalinity on the structure of phenol/formaldehyde resol resins [J]. J Appl Polym Sci, 2001, 82: 258-262.

共引文献32

同被引文献27

引证文献4

二级引证文献15

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部