摘要
氯代聚并苯同系物的能量和电子极化率与同系序数之间满足下列相关方程E=a Nβ+b, R≈ lα(或 απ ) =α′ Nβ′+b′,R≥ 0 .9990απ/ α(% ) =α″Nβ″+b″,R≥ 0 .9999N=2 n+1,为同系序数 ,n为苯环的结构单元数 β、β′、β″随同系分子的类型而变 。
WT5BZ]set correlation equation was contented with energy and electronic polarizability of chloro polyacence homologue and its homologous number. E = a N β+ b, R≈l α(或α π )=α′ N β′ + b′, R≥0.9990 α π/α(%)=α″ N β″ +b″, R≥0.9999 where,N=2n+1,are homologus number,n is structural unit numbers of benzene ring,β、 β′ and β″ are Varing with series of homologue,The calculated Values are well agree with literature ones.
关键词
氯代聚并苯
能量
电子极化率
同系序数
同系物
Chloro polyacence
Energy
Electronic polarizability
Homologous Number
