期刊文献+

铀在离子液体中的物种及电化学行为研究进展 被引量:3

Progress in Speciation and Electrochemistry Behaviors of Uranium in Ionic Liquids
在线阅读 下载PDF
导出
摘要 总结了近年来离子液体用于铀的水法及干法后处理相关的基础研究成果,主要内容包括铀在离子液体中的存在物种及电化学行为研究,归纳和分析了其中关键的科学问题。同时,基于当前的研究现状展望了离子液体在铀的净化分离方面的应用研究前景。 Herein, we reviewed the recent basic researches on the utility of ionic liquids in nuclear fuel reprocessing especially on speciation and electrochemical behaviors of uranium in ionic liquid, from which the key scientific issues on their practical application were summarized. Meanwhile, based on the current research situation, further basic studies on the speciation and electrochemistry of uranium in ionic liquids were prospected.
出处 《核化学与放射化学》 CAS CSCD 北大核心 2014年第2期65-74,共10页 Journal of Nuclear and Radiochemistry
基金 国家自然科学基金资助项目(No.11105162) 中国科学院核能先导专项资助项目(XDA03010404)
关键词 离子液体 物种 萃取 电化学 uranium ionic liquid speciation extraction electrochemistry
  • 相关文献

参考文献64

  • 1Earle M J, Seddon K R. Ionic liquids: green sol- vents for the future[J]. Pure Appl Chem, 2000: 1391-1398.
  • 2Shobukawa H, Tokuda H, Tabata S-I, et al. Prep- aration and transport properties of novel lithium ion- ic liquids[J]. Electrochim Acta, 2004, 50 (2-3) : 305-309.
  • 3Tadesse H, Luque R. Advances on biomass pre- treatment using ionic liquids: an overview[,J]. En- ergy Environ Sci, 2011, 4(10).. 3913-3929.
  • 4Hallett J P, Welton T. Room-temperature ionic liq- uids: solvents for synthesis and catalysis[J]. Chem Rev, 2011, 111(5): 3508-3576.
  • 5Han X, Armstrong D W. Ionic liquids in separa- tions[-J]. Ace Chem Res, 2007, 40(11)I 1079- 1086.
  • 6Yuan L Y, Peng J, Xu L, et al. Influence of )'-radi- ation on the ionic liquid[C4mim] [PFs ] during ex- traction of strontium ions[J]. Dalton Trans, 2008 (45) : 6358-6360.
  • 7Yuan L Y, Peng J, Xu L, et al. Radiation effects on hydrophobic ionic liquid[-C4 mim] ENTf2 ] during extraction of strontium ions[J]. J Phys Chem B, 2009, 113(26).. 8948-8952.
  • 8Yuan L Y, Peng J, Xu L, et al. Radiation-induced darkening of ionic liquid [,C4mim] [NTfz ] and its decoloration[J]. Radiat Phys Chem, 2009, 78(12).. 1133-1136.
  • 9Yuan L Y, Peng J, Zhai M, et al. Influence of )'- radiation on room-temperature ionic liquid [-Bmim] [-PF6] in the presence of nitric acid[,J]. Radiat Phys Chem, 2009, 78(7): 737-739.
  • 10Yuan L Y, Xu C, Peng J, et al. Identification of the radiolytic product of hydrophobic ionic liquid[C4mim] [NTfz] during removal of Srz+ from aqueous solution[J]. Dalton Trans, 2009 (38) : 7873-7875.

二级参考文献30

  • 1沈兴海,徐超,刘新起,褚泰伟.离子液体在金属离子萃取分离中的应用[J].核化学与放射化学,2006,28(3):129-138. 被引量:25
  • 2褚泰伟,秦丽,刘新起,王祥云.离子液体用于溶剂萃取铀酰离子的初步研究[J].核化学与放射化学,2007,29(3):146-150. 被引量:12
  • 3Allen D, Baston G, Bradley A E, et al. An Investiga- tion of the Radiochemical Stability of Ionic Liquids[J]. Green Chemistry, 2002, 4: 152-158.
  • 4Berthon L, Nikitenko S I, Bisel I, et al. Influence of Gamma Irradiation on Hydrophobic Room-Tem- perature Ionic Liquids 1- BuMelm ] [ PF6] and [BuMelm] [N (CF3SO2)2][ J]. Dalton Trans, 2006:2 526-2 534.
  • 5Shkrob I A, Chemerisov S D. The Initial Stages of Radiation Dammage in Ionic Liquids and Ionic Li- quid-Based Extraction Systems[J]. J Phys Chem B, 2007, 111: 11 786-11 793.
  • 6Harmon C D, Smith W H, Costa D A. Criticality Calculation for Plutonium Metal at Room Tempera- ture in Ionic Liquid Solutions [ J]. Radiat Phys Chem, 2001, 60:157-159.
  • 7Dai S, Ju Y H, Barnes C E. Solvent Extraction of Strontium Nitrate by a Crown Ether Using Room- Temperature Ionic Liquids[J]. J Chem Soc, Dalton Trans, 1999, 8:1 201-1 202.
  • 8Visser A E, Rogers R D. Room-Temperature Ionic Liquids: New Solvents for F-Element Separations and Associated Solution Chemistry[J]. J Solid State Chem, 2003, 171(1-2): 109-113.
  • 9Anderson C J, Choppin G R, Pruett D J, et al. Electrochemistry and Spectroscopy of UO2^2+ in Acidic AlCl3-EMIC[J]. Radiochim Acta, 1999, 84: 31-36.
  • 10Noriko A, Masayuki H, Yoshiyuki Y, et al. Appli- cation of Ionic Liquids to Pyrochemical Reprocessing Methods-Electrochemical Properties of Uranyl Ion in Ionic Liquids[C]//Proceedings of GLOBAL Tsukuba, 2005: 458.

共引文献32

同被引文献48

引证文献3

二级引证文献21

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部