摘要
本文报道以缺铝氢型丝光沸石催化烯或三环烯与六种含环醇的烷氧基化反应,以较高产率生成1,7,7—三甲基双环(2,2,1)庚基环烷基醚(或苯基烷基醚)。同时生成少量的(6,7,7—三甲基双环(2,2,1)庚基环烷基醚(或苯基烷基醚)副产物。含苯环产物通过Raney镍催化剂加氢也可得到标题化合物。
The alkoxylation reactions of camphene (1), tricyclene (2) with alcohols [cyclopentanol, cyclohexanol, tetra-hydrofurfuryl alcohol, benzyl alcohol, phenethyl alcohol, 2-phenylpropanol-(1)] are reported. these reactions lead to one-step syntheses of the title compounds (3a-3f), in which smali amount of by-products 6,7,7-trimethylbicyclo[2,2,1] heptyl alkyl ethers (4a-4f) are also formed at the same time. The hydrogenations of the product 3d, 3e and 3f give the title compounds 5g, 5h and 5i respectively. The relation between the odor and structure of the title compounds are also discussed.
出处
《广州化学》
CAS
1991年第3期28-34,共7页
Guangzhou Chemistry
基金
国家自然科学基金资助课题
