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β-NiOOH的制备及充放电性能 被引量:25

Preparation of β-NiOOH and Its Charge/Discharge Performance
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摘要 NiOOH was prepared by chemical oxidation of β Ni(OH) 2. The physical characteristics and the chemical composition of the product were characterized by XRD, TG/DTA and ICP measurements. β NiOOH and the mixed samples of β NiOOH with γ MnO 2 in different ratios were charged/discharged in constant current, the results show that the addition of γ MnO 2 improves the discharge voltage plateau of nickel electrode and the optimum ratio of γ MnO 2 in the electrode is 25%. The cut off voltage of nickel electrode should be above 0 V( vs .Hg/HgO). NiOOH was prepared by chemical oxidation of β Ni(OH) 2. The physical characteristics and the chemical composition of the product were characterized by XRD, TG/DTA and ICP measurements. β NiOOH and the mixed samples of β NiOOH with γ MnO 2 in different ratios were charged/discharged in constant current, the results show that the addition of γ MnO 2 improves the discharge voltage plateau of nickel electrode and the optimum ratio of γ MnO 2 in the electrode is 25%. The cut off voltage of nickel electrode should be above 0 V( vs .Hg/HgO).
作者 夏熙 潘仁
出处 《应用化学》 CAS CSCD 北大核心 2001年第1期76-78,共3页 Chinese Journal of Applied Chemistry
关键词 制备 充放电性能 锌镍电池 电极材料 氢氧化镍 NiOOH,preparation,charge/discharge performance
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参考文献2

  • 1Guo Z P,J Appl Electrochem,1999年,29卷,1417页
  • 2Xia X,J Electrochem Soc,1997年,144卷,L213页

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